Wolfe, a resident of Marshville, was arrested after being pulled over on his Harley Davidson by a NC Highway Patrol Trooper in Anson County on City Pond Road.
A witness to the shootings had reported to authorities the description of the motorcycle after deputies were called to the residence. Once they arrived they found both victims lying in the driveway, dead on the scene.
Reports have said that the shootings, which took place on Lanesboro Road in Union County, stemmed from an argument.
Facing charges of murder, Wolfe is being jailed in Union County without bail.